Biology Forums - Study Force

Science-Related Homework Help Chemistry Topic started by: firework6 on Jan 15, 2012



Title: reaction of nitrogen dioxide and carbon monoxide?
Post by: firework6 on Jan 15, 2012
For the reaction of nitrogen dioxide and carbon monoxide
NO2 + CO --->  NO + CO2

the following mechanism has been proposed at high temperatures:
(1) NO2 + NO2 -->  NO3 + NO(slow)
(2) NO3 + CO -->  NO2 + CO2(fast)

Choose from below for each species that is an intermediate in this mechanism. (you can choose more than one)

1)NO2
2)NO
3)CO
4)CO2
5)None of the above is an intermediate.


any ideas?


Title: reaction of nitrogen dioxide and carbon monoxide?
Post by: juliomarquez8 on Jan 15, 2012
The only intermediate is NO3 (it is present in the mechanism, but it is not a reactant or product overall). Therefore, 5 is correct.


Title: reaction of nitrogen dioxide and carbon monoxide?
Post by: Fire_Fly on Jan 16, 2012
On total reaction we can see that NO2 and CO are reactants while NO and CO2 are products. Intermediate doesn't exist as reactant nor product so the intermediate is NO3 then the answer is 5.