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Laboratory Help Introductory Courses Topic started by: feven on May 9, 2013



Title: chemistry help?,,, doing a lab on polyprotic acids and titration, please help?
Post by: feven on May 9, 2013
Given that 20.00 mL of phosphoric acid solution required 15.50 mL of 0.200M
NaOH for the first equivalent point. What is the molarity of the phosphoric acid?


Title: chemistry help?,,, doing a lab on polyprotic acids and titration, please help?
Post by: tomtom1234 on May 9, 2013
Use the formula:-
M1V1=M2V2
M1= molarity of 1st solution
V1= volume of 1st solution
M2= molarity of 2nd solution
V2= volume of 2nd solution
Here,
M1= ?
V1= 20mL
M2= .2 M
V2= 15.50mL
Putting in values we get,
M1*20 = .2*15.5
M1= .2*15.5/20 = .155M
So the molarity of phosphoric acid is 0.155M


Title: chemistry help?,,, doing a lab on polyprotic acids and titration, please help?
Post by: Leendr on May 9, 2013
NaOH + H3PO4 = NaH2PO4 + H20
The first equivalent point
Mol(NaOH) = 0.2 x 15.5  / 1000 =>
Mol(NaOH) = 0.0031 mol
Since this number of moles NaOH gives NaH2PO4
Then moles of NaH2PO4 used is 0.0031
Molarity (H3PO4) = 0.0031 x 1000 / 20.0 = 0.155M