Title: Arrhenius Equation Post by: UnicornPanda on Sep 24, 2012 I can't seem to wrap my head around this equation. I'm working on my post-lab right now and I am going through my data. My excel sheet is attached.
But I have no idea how to solve for k, much less ln(k). Help?! =/ Title: Re: Arrhenius Equation Post by: duddy on Sep 24, 2012 Use the values you found for k and click [ln] in your calculator, followed by the number, k. Or, better yet:
http://www.rapidtables.com/calc/math/Ln_Calc.htm Title: Re: Arrhenius Equation Post by: UnicornPanda on Sep 24, 2012 Yes, but I don't know how to solve for k at all. How do I find the activation energy or the frequency factor with the data that I have?
Title: Re: Arrhenius Equation Post by: duddy on Sep 24, 2012 Yes, but I don't know how to solve for k at all. How do I find the activation energy or the frequency factor with the data that I have? Was a formula provided? Title: Re: Arrhenius Equation Post by: UnicornPanda on Sep 24, 2012 Yes, but I don't know how to solve for k at all. How do I find the activation energy or the frequency factor with the data that I have? Was a formula provided? This is what I have: You will design this experiment to answer the following questions regarding this reaction: C_4H_9Cl + NaOH --> C_4H_9OH + NaCl The Arrhenius equation is as follows: k=Ae^(-E_a/RT) Where R is 8.3145 Joules/mol-K Title: Re: Arrhenius Equation Post by: duddy on Sep 24, 2012 Do we know little k, A, or -E_a ? We need to fill in 4 of the 5 variables in order to solve.
Title: Re: Arrhenius Equation Post by: UnicornPanda on Sep 24, 2012 Quote Do we know little k, A, or -E_a ? We need to fill in 4 of the 5 variables in order to solve. K= Chemical Reaction Rate A= Pre-Exponential Factor Ea= Activation Energy R= Gas Constant T= Temperature in Kelvin Title: Re: Arrhenius Equation Post by: duddy on Sep 24, 2012 I meant a quantitative value for them.
Title: Re: Arrhenius Equation Post by: duddy on Sep 24, 2012 Both the Arrhenius activation energy and the rate constant k are usually experimentally determined.
Title: Re: Arrhenius Equation Post by: UnicornPanda on Sep 25, 2012 Both the Arrhenius activation energy and the rate constant k are usually experimentally determined. That's what I'm not sure of. In my post-lab it asks me to plot the Arrhenius equation and what was the activation energy determined from the experiment. This is the data gathered from my experiment. It was water, acetone & 200 proof ethanol. with NaOH, blue indicator & t-butyl chloride #1-5 Ratio (1:1) 1.5mL water & 1.5mL Acetone 1. @44.5 C - 30 seconds for reaction to occur 2. @35 C - 1 minute 3. 26.5 C - 2:15 4. 54.3 C - 22 s 5. 64.0 C - 10 s 6. Water & Ethanol (1:1) 1.5mL each @ 26.5 C - 1:15 7. Water, Ethanol & Acetone (1:1:1) 1mL each @ 26.5 C - 1:55 8. Water & Ethanol (1:2) 1.5mL each @ 26.5 C - 1:05 Title: Re: Arrhenius Equation Post by: duddy on Sep 25, 2012 Have you plotted ln k (y) versus 1/T ? The activation energy of a reaction is determined from the slope of the Arrhenius plot.
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