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Science-Related Homework Help Chemistry Topic started by: UnicornPanda on Sep 24, 2012



Title: Arrhenius Equation
Post by: UnicornPanda on Sep 24, 2012
I can't seem to wrap my head around this equation. I'm working on my post-lab right now and I am going through my data. My excel sheet is attached.

But I have no idea how to solve for k, much less ln(k). Help?! =/


Title: Re: Arrhenius Equation
Post by: duddy on Sep 24, 2012
Use the values you found for k and click [ln] in your calculator, followed by the number, k. Or, better yet:

http://www.rapidtables.com/calc/math/Ln_Calc.htm


Title: Re: Arrhenius Equation
Post by: UnicornPanda on Sep 24, 2012
Yes, but I don't know how to solve for k at all. How do I find the activation energy or the frequency factor with the data that I have?


Title: Re: Arrhenius Equation
Post by: duddy on Sep 24, 2012
Yes, but I don't know how to solve for k at all. How do I find the activation energy or the frequency factor with the data that I have?

Was a formula provided?


Title: Re: Arrhenius Equation
Post by: UnicornPanda on Sep 24, 2012
Yes, but I don't know how to solve for k at all. How do I find the activation energy or the frequency factor with the data that I have?

Was a formula provided?

This is what I have:

You will design this experiment to answer the following questions regarding this reaction:
C_4H_9Cl + NaOH --> C_4H_9OH + NaCl

The Arrhenius equation is as follows:

k=Ae^(-E_a/RT)

Where R is 8.3145 Joules/mol-K


Title: Re: Arrhenius Equation
Post by: duddy on Sep 24, 2012
Do we know little k, A, or -E_a ? We need to fill in 4 of the 5 variables in order to solve.


Title: Re: Arrhenius Equation
Post by: UnicornPanda on Sep 24, 2012
Quote
Do we know little k, A, or -E_a ? We need to fill in 4 of the 5 variables in order to solve.

K= Chemical Reaction Rate
A= Pre-Exponential Factor
Ea= Activation Energy
R= Gas Constant
T= Temperature in Kelvin


Title: Re: Arrhenius Equation
Post by: duddy on Sep 24, 2012
I meant a quantitative value for them.


Title: Re: Arrhenius Equation
Post by: duddy on Sep 24, 2012
Both the Arrhenius activation energy and the rate constant k are usually experimentally determined.


Title: Re: Arrhenius Equation
Post by: UnicornPanda on Sep 25, 2012
Both the Arrhenius activation energy and the rate constant k are usually experimentally determined.

That's what I'm not sure of. In my post-lab it asks me to plot the Arrhenius equation and what was the activation energy determined from the experiment.

This is the data gathered from my experiment. It was water, acetone & 200 proof ethanol. with NaOH, blue indicator & t-butyl chloride

#1-5 Ratio (1:1) 1.5mL water & 1.5mL Acetone
1. @44.5 C - 30 seconds for reaction to occur
2. @35 C - 1 minute
3. 26.5 C - 2:15
4. 54.3 C - 22 s
5. 64.0 C - 10 s
6. Water & Ethanol (1:1) 1.5mL each @ 26.5 C - 1:15
7. Water, Ethanol & Acetone (1:1:1) 1mL each @ 26.5 C - 1:55
8. Water & Ethanol (1:2) 1.5mL each @ 26.5 C - 1:05


Title: Re: Arrhenius Equation
Post by: duddy on Sep 25, 2012
Have you plotted ln k (y) versus 1/T ? The activation energy of a reaction is determined from the slope of the Arrhenius plot.

(http://www.chem.canterbury.ac.nz/letstalkchemistry/ElectronicVersion/ElectronicVersionNew/chapter16/Pix/arrhenius.png)