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Hazardous Materials Technician by Weber
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Chapter 2
Regulations and Standards
Hazmat Situation
After bouncing from station to station, you’ve landed at station 6—on the edge of the industrial section of town. Over the last year you’ve been dispatched to your share of motor vehicle accidents in the area, several of them involving tanker trucks from a local refinery.
What questions go through your mind as you respond?
Response Considerations
Who regulates the refinery industry?
What kind of hazardous materials training do the drivers of the tanker have?
Response Considerations
Who needs be notified if the tanker leaks at one of these motor vehicle accidents?
What type of hazardous materials training am I required to have to respond to these accidents?
Objectives
Describe the requirements of HAZWOPER in regard to hazardous materials emergency response at the hazardous materials technician level.
List the five levels of hazardous materials training defined in HAZWOPER.
Describe the training requirements at the hazardous materials technician level according to HAZWOPER.
Objectives
Summarize the requirements of the Resource Conservation and Recovery Act (RCRA).
Name the key EPA regulations that affect hazardous materials response and training and summarize their requirements.
Summarize the requirements of the Hazardous Materials Regulations (HMR).
Objectives
Describe how the global harmonization effort affects, and will affect, response to hazardous materials releases at the hazardous materials technician level.
Describe the differences between the HAZWOPER regulation and the NFPA 472 (2008) standard regarding hazardous materials technician proficiencies and training.
Objectives
Describe the role of voluntary consensus standard organizations and their relationship to hazardous materials response.
Legal Foundation of Hazardous Materials Response
Rules
Laws
Regulations
Ordinances
Consensus standards
Government levels
Federal
Tribal
State
Local
Legal Foundation of Hazardous Materials Response
Three agencies are primarily responsible for hazardous material regulation:
Environmental Protection Agency (EPA)
Occupational Safety and Health Administration (OSHA)
Department of Transportation (DOT)
U.S. Occupational Safety and Health Administration
HAZWOPER
29 CFR 1910.120
Respiratory Protection
29 CFR 1910.134
Hazard Communication–Haz Com
29 CFR 1910.1200
U.S. Occupational Safety and Health Administration
OSHA States
FIGURE 2-1 States and territories that have adopted their own version of HAZWOPER for all workers are shown in red, states that have adopted their own version of HAZWOPER for government workers only are shown in blue, and states that have not adopted their own regulations are shown in white. Your state jurisdiction can have a significant impact on how you respond to hazardous materials emergencies.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph A
HAZWOPER applies to:
Cleanup operations required by a governmental body at uncontrolled hazardous waste sites.
Corrective actions involving clean-up at Resource Conservation and Recovery Act (RCRA) sites.
Voluntary clean-up operations at governmentally recognized uncontrolled hazardous waste sites.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph A
HAZWOPER applies to:
Hazardous waste operations at treatment, storage and disposal (TSD) facilities.
Emergency response operations for releases of, or substantial threats of releases of, hazardous substances without regard to the location of the hazard.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph F
Medical surveillance
Medical exam before assignment
Medical exam every 1–2 years thereafter
Medical exam upon chemical exposure
Medical exam upon leaving assignment
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph F
Covered personnel are:
Employees who are, or may become, exposed to hazardous substances at or above permissible exposure levels (PEL) for thirty or more days per year.
Employees who wear respirators for thirty or more days per year.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph F
Covered personnel are:
Employees who are injured, become ill, or develop signs and symptoms due to a job related exposure.
Members of hazardous materials response teams.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph G
Hazards shall be controlled using:
Engineering controls
Work practices
Personal protective equipment (PPE)
Should be applied in this order to protect employees from exposure to hazardous substances and safety and health hazards.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph G
PPE program components:
PPE selection criteria that are based upon site hazards.
How to use the PPE and limitations of the equipment.
Work mission duration.
PPE maintenance and storage.
PPE decontamination and disposal.
PPE training and proper fitting.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph G
PPE program components:
PPE donning and doffing procedures.
PPE inspection prior to, during, and after use.
Evaluation of the effectiveness of the program.
Limitations during temperature extremes, heat stress, and other appropriate medical considerations.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Emergency response to Hazmat incidents
Public safety agencies
Private sector
Emergency response plans
Emergency response procedures
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Emergency Response Plans
Preemergency planning and coordination with outside agencies.
Personnel roles, lines of authority, training, and communication.
Emergency recognition and prevention.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Emergency Response Plans
Safe distances and places of refuge.
Site security and control.
Evacuation routes and procedures.
Decontamination.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Emergency Response Plans
Emergency medical treatment and first aid to exposed victims.
Emergency alerting and response procedures.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Emergency Response Plans
Critique of any previous hazardous materials incident responses and any follow-up actions.
Personal protective equipment (PPE) and other emergency equipment.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Procedures should be developed for handling an emergency response.
These response procedures require:
Use of an incident command system (ICS).
Identification of all hazardous substances and conditions present.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
These response procedures require:
Implementation of appropriate emergency operations using the correct PPE.
Use of SCBA until appropriate air monitoring has been performed.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Response procedures
The buddy system must be used in the hot zone.
Backup personnel must be available for rescue of hot zone personnel using the two-in/two-out rule.
ALS personnel must be on standby with medical equipment and transport capability.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Response Procedures
An experienced and knowledgeable safety officer must be appointed.
The safety officer has the authority to terminate or alter emergency activities immediately and unilaterally.
Decontamination procedures must be implemented
Manufacturers SCBA bottles may be interchanged in certain situations.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Skilled support personnel
Essential personnel without HAZWOPER certification may enter hot zone in an emergency if they receive a safety briefing:
Instruction on use of appropriate PPE
Chemical hazards involved
Duties to be performed
Example: heavy equipment operators
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Awareness level
Employees
Use DOT Emergency Response Guidebook (ERG)
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
RAIN:
Recognize hazardous materials
Self evacuation
Isolation of area
Notification of appropriate emergency response agency
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Operations Level
Protect nearby persons and property and environment
Defensive actions
Without coming into contact with hazardous substance
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Technician Level
Stop the hazardous materials release
Offensive actions
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Have the ability to:
Implement employer’s emergency response plan.
Use field survey instruments to verify and/or determine the nature of the release.
Function within the ICS.
Select and use PPE.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Technician Level
Understand hazard and risk assessment techniques.
Perform advanced product control, containment and/or confinement techniques.
Understand and implement decontamination procedures.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Technician Level
Understand termination procedures.
Understand basic chemical and toxicological terminology and behavior.
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Specialist Level
Support technician level personnel
Implement the local emergency response plan
In-depth knowledge
Develop site safety plan
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Incident Commander Level
Assume control of hazmat incident
Implement ICS
Implement emergency response plan
Know of state emergency response plan
Know federal response capabilities
Understand risks of working in PPE
Understand importance of decontamination
U.S. Occupational Safety and Health Administration
HAZWOPER: Paragraph Q
Medical surveillance
Baseline physical exam according to Paragraph F
Medical consultation upon chemical exposure
U.S. Occupational Safety and Health Administration
Respiratory Protection (29 CFR 1910.134)
Protects employees from hazardous atmospheres
Employer must provide respiratory protection
Employer must provide training
Employer must provide medical evaluation and fit testing
U.S. Occupational Safety and Health Administration
Hazard Communication (HAZCOM—29 CFR 1910.1200)
This law requires:
Employee right to know
Employers must inform employees of hazardous chemicals in workplace
Material Safety Data Sheets (MSDS)
Health emergencies
Spill response
U.S. Environmental Protection Agency
Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) and Federal Environmental Pesticide Control Act (FEPCA)
Regulates sale, distribution and use of pesticides
U.S. Environmental Protection Agency
Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) and Federal Environmental Pesticide Control Act (FEPCA)
Protection of human health and the environment
Burden of proof on manufacturers
Enforce compliance
Regulatory framework
U.S. Environmental Protection Agency
FIFRA and FEPCA
Pesticide Product Labeling System (PPLS)
Label must contain:
Name and address of the producer, registrant, or person for whom produced
Restricted use statement (when required)
Product name, brand, or trademark
U.S. Environmental Protection Agency
FIFRA and FEPCA
Pesticide Product Labeling System (PPLS)
Label must contain:
Ingredient statement
Signal word—including skull and cross bones (when required)
“Keep Out Of Reach of Children” (KOOROC)
U.S. Environmental Protection Agency
FIFRA and FEPCA
Pesticide Product Labeling System (PPLS)
Label must contain:
The cautionary statements—including hazards to humans and domestic animals
EPA registration number
EPA establishment number
U.S. Environmental Protection Agency
FIFRA and FEPCA
Pesticide Product Labeling System (PPLS)
Label must contain:
Storage and disposal statements
Referral statement to direction for use in booklet (when supplemental labeling is used)
Net weight or measure of contents
U.S. Environmental Protection Agency
FIFRA and FEPCA
Pesticide Label
FIGURE 2-2 An example of the key features of pesticide labels. The EPA requires the inclusion of specific information that can be very helpful during hazardous materials emergencies.
U.S. Environmental Protection Agency
FIFRA and FEPCA
EPA Registration Number
123–456–789
Manufacturer—Pesticide—Distributor
Some pesticide registration numbers will not have a second dash and a distributor number
U.S. Environmental Protection Agency
FIFRA and FEPCA
Signal words
DANGER is used for the most highly toxic pesticides
WARNING is used for moderately toxic pesticides
CAUTION is used for less toxic pesticides
U.S. Environmental Protection Agency
Clean Air Act of 1970 (CAA)
National air quality standards
Criteria air pollutants
Sulfur dioxide
Nitrogen dioxide
Ozone
Carbon monoxide
Lead
Particulate matter
U.S. Environmental Protection Agency
Clean Air Act of 1970 (CAA)
General welfare of the public
U.S. Environmental Protection Agency
Clean Water Act (CWA)
Response and cleanup of emergency releases of chemicals into waterways
Established:
National Contingency Plan (NCP)
National Response Team (NRT)
U.S. Environmental Protection Agency
Clean Water Act (CWA)
National Oil and Hazardous Substances Pollution Contingency Plan (NCP)
Federal response structure
U.S. Environmental Protection Agency
Clean Water Act (CWA)
National Oil and Hazardous Substances Pollution Contingency Plan (NCP)
Activities performed under NCP:
Preparedness planning and coordination for response to hazmat discharge
Notification and communications
Response operations at the scene of a discharge or release
U.S. Environmental Protection Agency
Clean Water Act (CWA)
Representatives from many agencies involved in hazardous materials response
Operations
Logistics
Finance
Chaired by the EPA
Vice chaired by the U.S. Coast Guard
U.S. Environmental Protection Agency
Toxic Substances Control Act of 1976 (TSCA)
Regulate the manufacture, distribution, use, and disposal of chemicals
U.S. Environmental Protection Agency
Toxic Substances Control Act of 1976 (TSCA)
Warning labels:
Name and address of the manufacturer
Common name of the chemical
Health hazards
Environmental hazards
Exposure hazards
Actions to minimize any of the aforementioned hazards
U.S. Environmental Protection Agency
Resource Conservation and Recovery Act (RCRA)
Cradle to grave regulation of hazardous waste
Hazardous waste generator is financially liable
Reduced illegal dumping
Periodically tour and review RCRA waste sites in your jurisdiction
U.S. Environmental Protection Agency
Resource Conservation and Recovery Act (RCRA)
RCRA requires:
Properly characterize the waste
Limits the time hazardous waste may be stored on their premises before disposal
Dictates safe storage conditions
Requires the use of hazardous waste manifests during transport
U.S. Environmental Protection Agency
Resource Conservation and Recovery Act (RCRA)
RCRA requires:
licensing of hazardous waste haulers
regulates disposal facilities
hazardous waste manifest must be returned to the original generator
U.S. Environmental Protection Agency
Resource Conservation and Recovery Act (RCRA)
Waste classification categories:
Universal
Characteristic:
Flammability
Reactivity
Corrosiveness
Toxicity
Listed
U.S. Environmental Protection Agency
Resource Conservation and Recovery Act (RCRA)
Passed by Congress in response to several significant environmental disasters including:
Love Canal in New York
Valley of the Drums
Brooks, Kentucky
Chemical waste dumpsite from 1967 to 1977
U.S. Environmental Protection Agency
Resource Conservation and Recovery Act (RCRA)
Passed by Congress in response to several significant environmental disasters including:
Valley of the Drums
Tens of thousands of leaking 55-gallon drums
In 1979 EPA started conducting cleanup operations under CWA and CERCLA
U.S. Environmental Protection Agency
Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA)
“Superfund”
Authority for a federal response
Liability for responsible party
Established trust fund for cleanup operations
Long-term and short-term operations
U.S. Environmental Protection Agency
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Title I—response and liability (HAZWOPER)
Title II—miscellaneous provisions
Title III—emergency planning and community right to know (EPCRA)
Title IV—interior air quality research and radon
U.S. Environmental Protection Agency
Emergency Planning and Community Right-to-Know Act (EPCRA)
Title III of SARA:
Emergency planning (sections 301–303)
Emergency release notification (section 304)
U.S. Environmental Protection Agency
Emergency Planning and Community Right-to-Know Act (EPCRA)
Title III of SARA:
Hazardous chemical inventory (sections 311 and 312)
Toxic chemical release inventory (section 313)
U.S. Environmental Protection Agency
EPCRA
Requires the formation of State Emergency Response Committees (SERC)
Requires the formation of Local Emergency Planning Committees (LEPC)
U.S. Environmental Protection Agency
EPCRA
Local Emergency Planning Committees (LEPCs) are comprised of local stakeholders:
Industry
Public safety
Nonprofit organizations
Review the emergency response plan on an annual basis
U.S. Environmental Protection Agency
Oil Pollution Act (OPA)
Regulates the petroleum industry
Producers
Carriers
Refineries
Must develop emergency response plans, training programs, exercises, and have adequate spill resources available
Funded by tax on oil
U.S. Department of Transportation
Hazardous Materials Regulations (HMR)
U.S. DOT regulates hazardous materials during transport
49 CFR Parts 100 to 185
U.S. Department of Transportation
Hazardous Materials Regulations (HMR)
Hazardous materials shipments must be:
Properly characterized
Safely packaged
Appropriately marked and labeled
Accompanied by shipping papers during transportation
U.S. Department of Transportation
The Hazardous Materials Regulations
Placards
Table 1 materials must be placarded in any quantity
Table 2 materials must be placarded when the aggregate gross weight of all hazardous materials in the non-bulk packages is over 454 kg (1,001 lbs)
U.S. Department of Transportation
The Hazardous Materials Regulations
Placards
Illegal to place a label on a package or a placard on a vehicle if it does not contain that hazardous material during transportation
U.S. Department of Transportation
The Hazardous Materials Regulations
Placards: Table 1 Materials
FIGURE 2-3 DOT placarding requirements: Table 1 materials must be placarded in any quantity, and Table 2 materials must be placarded when more than 1001 pounds of the material is being transported. Courtesy of the U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration.
FIGURE 2-3 (continued) DOT placarding requirements: Table 1 materials must be placarded in any quantity, and Table 2 materials must be placarded when more than 1001 pounds of the material is being transported. Courtesy of the U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration.
U.S. Department of Transportation
The Hazardous Materials Regulations
U.S. DOT Employees
Receive initial training that at a minimum includes:
General awareness/familiarization training
Function-specific training
Safety training
U.S. Department of Transportation
The Hazardous Materials Regulations
U.S. DOT Employees
Receive initial training that at a minimum includes:
Security awareness training
In-depth security training (when applicable, on the written transportation security plan of the employer)
U.S. Department of Transportation
Global Harmonization System (GHS)
Reduce inconsistencies between United States and international hazmat regulations
FIGURE 2-4 An example of the sometimes drastic differences in placarding regulations in the United States versus in Europe. In the United States anhydrous ammonia is placarded as a nonflammable gas (left); in Europe it is placarded as a poisonous and corrosive gas (right). Photos courtesy of Chris Weber, Dr. Hazmat, Inc.
U.S. Department of Transportation
Examples of GHS Changes:
Proper shipping names
Hazard classes
Packing groups
Special provisions
Packaging authorizations
Air transport of limited quantities
Vessel stowage requirements
U.S. Department of Transportation
Global Harmonization System (GHS)
GHS Pictograms
FIGURE 2-5 Nine labels used to identify hazardous materials in the Global Harmonization System (GHS). Top row: explosive (left), flammable (middle), and oxidizer (right). Middle row: compressed gas (left), corrosive (middle), and poison (right). Bottom row: the cautionary symbol used for multiple hazards (left), the health hazard symbol used for such materials as carcinogens (middle), and environmental hazards (right). As a hazardous materials technician you will soon encounter these labels much more often as global harmonization becomes more widespread. Art by David Heskett.
U.S. Department of Transportation
Federal Aviation Administration (FAA)
FAA Temporary Flight Restrictions in the Vicinity of Disaster/Hazard Areas (14 CFR 91.137)
Temporarily close the airspace above and near the location of the hazardous materials release
Accredited news representatives have been excepted from this rule (although they must file a flight plan)
National Fire Protection Association (NFPA)
Provides a “standard of care”
NFPA 472 (2008 edition)
Guidance for fire service and law enforcement personnel responding to hazardous materials and WMD incidents
NFPA 473 (2008 edition)
Guidance to emergency medical service personnel responding to hazardous materials and WMD incidents
ASTM, ANSI, and other Standards Organizations
ASTM International
American National Standards Institute (ANSI)
American Petroleum Institute (API)
Formed to increase safety, standardize procedures, and generally improve the efficiency of business and industry
Liability
Arises out of your actions at a hazardous materials emergency when your actions are negligent or criminal in nature
Gross negligence occurs when an individual acts in an outrageously negligent manner
Liability
Negligence:
A duty to act, and a failure to do so—hazmat technicians as part of the hazardous materials response team automatically have a duty to act
Failure to conform to the generally accepted standard of care (such as HAZWOPER and NFPA 472)
A loss or damage was suffered due to the allegedly negligent actions
Liability
Types of Liability:
Vicarious liability—when one person or agency is responsible for the actions of another person
Liability
Types of Liability:
Respondeat superior—when the employer is responsible for the actions of the employee; however, if the employee acts outside of the scope of employment the employee may be personally liable for their negligent actions
Liability
Types of Liability:
Joint and several liability—allows the victim to recover damages from all responsible parties
Landowner liability—property owners are responsible for damages arising out of the use of that property, such as poorly maintained or defective equipment
Liability
Criminal Liability:
Laws are violated and thereby a criminal act is committed
Very unusual for emergency response personnel
Common Law Nuisance—an activity that interferes with the use of private property (private nuisance) or interferes with public health and safety (public nuisance)
Liability
Criminal Liability:
Very unusual for emergency response personnel
Common Law Negligence—a wrongful act that causes damage or injury; the act can be willful or negligent
Statutory Liability—accountability imposed through federal, state, and local laws and ordinances
Summary
Hazardous materials and WMD incident response is dangerous
Regulations and standards are in place to protect hazmat technicians and the public:
OSHA
EPA
DOT
NFPA
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