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Why is the aliphatic amine a stronger base than the aromatic amide?

askal

wrote...

Posts: 37

Rep:

12 years ago

Why is the aliphatic amine a stronger base than the aromatic amide?

Why is the aliphatic amine a stronger base than the aromatic amide?

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2 Replies

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Replies

rkoch

wrote...

#1

12 years ago

In aromatic amide, the lone pair of nitrogen is dispersed over the aromatic ring, thus decreasing the electron density on nitrogen. That's why it is weaker base than aliphatic amine.

tlello

wrote...

#2

12 years ago

All amines are stronger bases than amides.
The other answer is completely correct explaining the basicities of amines.

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