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country3313 country3313
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6 years ago
What experimental evidence can you cite in support of the hypothesis that the electronegativi-ty of a hybridized atom increases with increasing s character?
 
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6 years ago
Evidence for this effect can be seen in the observation that the positive end of the di-pole moment in N  C  Cl is on the Cl atom. We conclude that the carbon atom in the cyanide group is more electronegative than a chlorine atom. One can also consider the acidity of ethane, ethene, and acetylene. As the s-character of the hybridization increases (ethane, ethene, acetylene), the pKa decreases ( >50 for ethane, 44 for ethane, and 25 for acetylene). Since pKa is inversely related to electronegativity, it is clear that as the s-character increases, the electronegativity also increases.
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