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sweetangel sweetangel
wrote...
Posts: 29
Rep: 0 0
12 years ago
Could someone please help me with these questions. thanks a lot.

Predict whether the following substances would be either ionic or molecular
compounds. Justify your prediction.
i)   CaBr2
ii)   Na3N
iii)   CH4

b)  Rank the bonds in these compounds in order of decreasing ionic character.
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wrote...
Valued Member
12 years ago
i)   CaBr2
ii)   Na3N
iii)   CH4

Top two are ionic (made up of a metal and non-metal), last one is molecular (two non-metals).

Hope that's a good start to your question!
wrote...
12 years ago
Okay, lets start with some definitions:

An IONIC COMPOUND: Consist of a NONMETAL (right side and in the middle of the periodic table) and a METAL(left side of the periodic table). More specifically an ionic compounds consist of 2 ions (cation =+ charge and an anion=- charge) with a net charge of 0.

Examples: NaCl, AgCl, MgO...

A molecular compound: consist of two nonmetals (on the right side of the periodic table) and does not necessarily have a net charge of 0

Examples: CH(4), C2H6 (the numbers are underscript)

Alright here we go.

a) Ca is on the left(metal) Br is on the right(nonmetal) so from my definition above it is an Ionic Compound

B) Na is a metal and N is a nonmetal therefore it is an Ionic Compound

C) C is a nonmetal and H is also a nonmetal therefore it is a Molecular Compound

Ionic Character


Group
Period 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 H
2.1
He
0
2 Li
0.98
Be
1.57
B
2.04
C
2.55
N
3.04
O
3.44
F
3.98
Ne
0
3 Na
0.93
Mg
1.31
Al
1.61
Si
1.9
P
2.19
S
2.58
Cl
3.16
Ar
0
4 K
0.82
Ca
1
Sc
1.36
Ti
1.54
V
1.63
Cr
1.66
Mn
1.55
Fe
1.83
Co
1.88
Ni
1.91
Cu
1.9
Zn
1.65
Ga
1.81
Ge
2.01
As
2.18
Se
2.55
Br
2.96
Kr
0
5 Rb
0.82
Sr
0.95
Y
1.22
Zr
1.33
Nb
1.6
Mo
2.16
Tc
1.9
Ru
2.2
Rh
2.28
Pd
2.2
Ag
1.93
Cd
1.69
In
1.78
Sn
1.96
Sb
2.05
Te
2.1
I
2.66
Xe
2.6
6 Cs
0.79
Ba
0.89
La
1.1
Hf
1.3
Ta
1.5
W
2.36
Re
1.9
Os
2.2
Ir
2.2
Pt
2.28
Au
2.54
Hg
2
Tl
2.04
Pb
2.33
Bi
2.02
Po
2
At
2.2
Rn
0
7 Fr
0.7
Ra
0.89
Ac
1.1
Rf
Db
Sg
Bh
Hs
Mt
Uun
Uuu
Uub
Lanthanides Ce
1.12
Pr
1.13
Nd
1.14
Pm
1.13
Sm
1.17
Eu
1.2
Gd
1.2
Tb
1.1
Dy
1.22
Ho
1.23
Er
1.24
Tm
1.25
Yb
1.1
Lu
1.27
Actinides Th
1.3
Pa
1.5
U
1.38
Np
1.36
Pu
1.28
Am
1.3
Cm
1.3
Bk
1.3
Cf
1.3
Es
1.3
Fm
1.3
Md
1.3
No
1.3
Lr

Key:

White=
No data
0-.66
.66-1
1-1.33
1.33-1.66
1.66-2
2-2.33
2.33-2.66
2.66-

Generally, ionic characters increase as you go right and upwards on a periodic table.
wrote...
12 years ago
Ionic compounds form when there is an electronegativity difference between atoms greater than 2.5. Also, the simpler explanation is that generally (not exactly always), bonds between metals and non-metals are ionic. What happens is that the electron sharing is so unequal, that one atom (the less electronegative) somewhat just gives up its electrons completely to the other atom.

A) Ca2+ is a metal, and Br2 is a halogen (non-metal). Thus, ionic.
B) Na+ is metal, and N is a non-metal. Thus, ionic.
C) CH4; both atoms are non-metals. The EN of C is 2.5, and the EN of H is 2.2. There is not a significant electronegativity difference, thus it is not ionic.
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