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Pikachau Pikachau
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2 years ago
Why does benzene have a much higher boiling point (80 °C) than hexane (69 °C), even though they have the same number of carbons?

▸ Benzene has fewer hydrogens than hexane.

▸ Benzene is much more polar than hexane which enhances the attractive forces between molecules and raises the boiling point.

▸ Benzene is planar and has delocalized electron density which increases the attractive forces between molecules and raises the boiling point.

▸ Hexane has more Kekulé structures than benzene.

▸ Benzene can covalently bond to another benzene molecule which increases its boiling point.
Textbook 
General Chemistry: Principles and Modern Applications

General Chemistry: Principles and Modern Applications


Edition: 11th
Authors:
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Nigel C.Nigel C.
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2 years ago
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