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fishnchips fishnchips
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11 years ago
25.00 mL of a 0.12 M weak acid, HA, was titrated with 0.1 M NaOH. The pH of the solution was 4.2 after 10 mL of NaOH was added. What is the dissociation constant of the acid?
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wrote...
11 years ago
You need to use the Henderson-Hasselbalch equation

pH = pKa + log([base]/[acid])

Calculate how much acid is left and how much salt is formed and put it in the equation

I get an answer of 4.5 for pKa
Ka = 3.16 x 10^-5
wrote...
11 years ago
pH = pKa + log(A-/HA)

mmol HA at start = 3.0 (25 mL x 0.12 M)
Added NaOH = 1 mmol (10mL x 0.10 M)
[A-] = 1 mmol/vol
[HA] = 2 mmol/vol
log(1/2) = -0.30
pH = 4.2 = pKa + log(1/2)
pKa = 4.5 so Ka 3.2x10^-5
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