Clamp the coin between two terminals, one against each face of the coin. Set up the circuit and use your multimeter to measure the voltage, V, across the coin. The voltage drop will be small, so you will need a sensitive meter.Then open the circuit, put the multimeter in series and measure the current I in the circuit. Now, since V = IR, you can calculate R, the resistance of the coin in ohms. You may also be able to measure the resistance of the coin directly using the meter's setting for measuring resistance in ohms. It will be a very low number and the multimeter may not be useful for this purpose.
Once you know the resistance, calculate the conductance as 1/R. It is sometimes measured in mhos(mho = ohm backwards, no kidding). However, the official SI unit of measure for electrical conductance is the siemens (S) which is defined as an inverse ohm (ohm^-1). To convert conductance to conductivity, multiply by the area of the coin and divide by its thickness. Conductivity, ?, is the reciprocal (inverse) of electrical resistivity, ?, and has the SI units of siemens per meter (S·m-1) and CGSE units of inverse second (s?1). See:
http://en.wikipedia.org/wiki/Siemens_%28unit%29If you have an actual silver coin, it will likely contain about 90% silver, so your answer will be less than the conductivity of pure silver, which has the highest conductivity of any metal at 6.3 x 10^7 S-m^-1. For more on conductivity, see:
http://en.wikipedia.org/wiki/Electrical_conductivityThe above reference is a bit technoiud so here are some others:
http://www.newton.dep.anl.gov/askasci/eng99/eng99507.htmhttp://www.ehow.com/how_2046943_test-conductivity-metal.html