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Fightboy Fightboy
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9 years ago
Trifluoroacetic acid has a pka of 0.23. If this compound is a solution with a pH of 4.23, what is the ratio of trifluoroacetic acid to trifluoroacetate?
Would the answer be 1:10,000?? That's the answer i got but the answer key said 1:1,000
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rsb
wrote...
9 years ago
Found this online:

Quote
use the henderson-hasslebach equation
pH = pKa + log ( [A-]/[HA] )
4.23 = 0.23 + log (A-/HA)
4.00 = log [A-/HA]
10^4.00 = log A-/HA]
You will have 10000 times more conjugate base than acid, or 0.0001 acid to each conjugate base.

This is a horrible buffer, (as you can see).
For a good buffer we want the pKa to be as close to the pH as possible, that way we can have equal parts weak acid and conjugate base
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