Top Posters
Since Sunday
d
4
N
3
3
R
3
k
3
o
3
Z
3
j
3
s
3
d
3
J
3
1
3
New Topic  
karotop02 karotop02
wrote...
Posts: 150
Rep: 0 0
2 years ago
What is an appropriate stepwise synthesis for the following synthesis that uses 1-propanol as the only source of carbon and any other reagents as needed?




▸ 1-propanol reacts with PCC/CH2Cl2 to yield an intermediate that reacts with LDA to yield intermediate X, which has a resonance form Y. 1-propanol also reacts with PCl3 to yield an intermediate Z that reacts with intermediate X, which undergoes the following series of reactions to yield the product: 1. Na2Cr2O7/H2SO4/H2O; 2. Excess CH3CH2CH2OH/H2SO4.

▸ 1-propanol reacts with PCC/CH2Cl2, then the product reacts with LDA to produce intermediate X, which has resonance forms. 1-propanol reacts with PCl3, then the product reacts with intermediate X to yield intermediate Y. Intermediate Y reacts with NaBH4/CH3OH to yield the product.

▸ 1-propanol reacts with PCl3 to yield intermediate X. 1-propanol also undergoes the following reaction sequence: 1. Na2Cr2O7/H2SO4/H2O; 2. excess CH3CH2CH2OH/H2SO4; 3. LDA; 4. Intermediate X. This yields the product.

▸ A or B

▸ A or C
Textbook 
Organic Chemistry

Organic Chemistry


Edition: 4th
Author:
Read 40 times
1 Reply
Replies
Answer verified by a subject expert
dreamnluvdreamnluv
wrote...
Posts: 158
Rep: 1 0
2 years ago
Sign in or Sign up in seconds to unlock everything for free
More solutions for this book are available here
1

Related Topics

karotop02 Author
wrote...

2 years ago
This calls for a celebration Person Raising Both Hands in Celebration
wrote...

Yesterday
This site is awesome
wrote...

2 hours ago
Good timing, thanks!
New Topic      
Explore
Post your homework questions and get free online help from our incredible volunteers
  1570 People Browsing
Related Images
  
 1203
  
 404
  
 256
Your Opinion
What's your favorite math subject?
Votes: 559

Previous poll results: Who's your favorite biologist?