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Making ice chart help
LowriderMach
LowriderMach
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9 years ago
9 years ago
Making ice chart help
I did poorly on this chapter and the ice tables were one reason. Can anyone explain them in detail? I have these two questions! thanks
1) A(g) + 2B(g) ---> 2C(g)
If .02 mol A + 0.01 mol B are placed in a 2.00 L vessel at equilibrium B is found to be 0.0042M what is Kc?
2) What is the pH of a solution that is 0.012M in HA + has a Ka of 3.2x10^-8
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Laser_3
wrote...
#1
Subject Expert
9 years ago
Hi LowriderMach,
[A] = .02/2 = .01M
[B ]i = .01/2 = .005M
[B ]eq = .0042M
A(g) + 2B(g)
2C(g)
Initial .01 .005 0
Change -x -2x +2x
Equilibrium .01-x .0042 2x
From [B ], we can see that
.005-2x = .0042
.0008 = 2x
x = .0004
[A]eq = .01-.0004 = .0096M
[C]eq = 2*.0004 = .0008
Kc = [A]*[B ]^2/[C]^2
Kc = .0096*.0042^2/.0008^2
Kc = .2646
2)
HA + H2O
A- + H3O+
Initial .012 0 ~0
Change -x +x +x
Equilibrium .012-x x x
Ka = x^2/(.012-x)
If Ka is less than 10^-4, you can approximate that .012-x ~ .012
Ka = x^2/.012
3.2*10^-8 = x^2/.012
x^2 = 3.8*10^-10
x = .00002 = 2*10^-5
since x is the concentration of H3O+
-log(x) = pH
-log(2*10^-5) = 4.7
Hope this helps,
Laser
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LowriderMach
Author
wrote...
#2
9 years ago
Quote from: Laser_3 (9 years ago)
Hi LowriderMach,
[A] = .02/2 = .01M
[B ]i = .01/2 = .005M
[B ]eq = .0042M
A(g) + 2B(g)
2C(g)
Initial .01 .005 0
Change -x -2x +2x
Equilibrium .01-x .0042 2x
From [B ], we can see that
.005-2x = .0042
.0008 = 2x
x = .0004
[A]eq = .01-.0004 = .0096M
[C]eq = 2*.0004 = .0008
Kc = [A]*[B ]^2/[C]^2
Kc = .0096*.0042^2/.0008^2
Kc = .2646
2)
HA + H2O
A- + H3O+
Initial .012 0 ~0
Change -x +x +x
Equilibrium .012-x x x
Ka = x^2/(.012-x)
If Ka is less than 10^-4, you can approximate that .012-x ~ .012
Ka = x^2/.012
3.2*10^-8 = x^2/.012
x^2 = 3.8*10^-10
x = .00002 = 2*10^-5
since x is the concentration of H3O+
-log(x) = pH
-log(2*10^-5) = 4.7
Hope this helps,
Laser
you rock! thanks for this
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