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Propylene (propene) undergoes free radical polymerization with benzoyl peroxide, but does not ...

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Propylene (propene) undergoes free radical polymerization with benzoyl peroxide, but does not ...

Propylene (propene) undergoes free radical polymerization with benzoyl peroxide, but does not produce very long chains. What is the most reasonable explanation for this result?

▸ Polypropylene has very few H-C bonds.

▸ There are C-H bonds at allylic positions in propylene.

▸ There is a double bond in propylene.

▸ There are C-C bonds at vinylic positions in propylene.

▸ The chain is not able to undergo hydrogen abstraction.

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Organic Chemistry

Edition: 4^th

Author: Klein

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