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merrisara merrisara
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2 years ago
Why does the expected stretching absorption of the C=O bond in compounds I and II differ, as shown below?




▸ Compound I has more possible resonance structures, increasing the single bond character of the carbonyl group.

▸ Compound II has more possible resonance structures, increasing the single bond character of the carbonyl group.

▸ Compound I has a C to O bond with more single bond character than that of compound II, increasing the expected stretching absorption of the bond.

▸ Only compound II has resonance, causing it to have a higher stretching absorption.

▸ Only compound I has resonance, causing it to have a higher stretching absorption.
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Organic Chemistry

Organic Chemistry


Edition: 4th
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szsz
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