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ASJ ASJ
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11 years ago
I just learned about redox reactions and need help balancing this reaction using changes of oxidation numbers.  It would be great if you could explain it step-by-step:

Here is the unbalanced equation: KClO3(s)?KCl(s)+O2(g)   (the 3 and the 2 should be in subscript)

THANKS!
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wrote...
11 years ago
KClO3(s)?KCl(s)+O2(g)

Cl in ClO3 = 5+ and becomes 1- in KCl, gains 6 e-, reduced
O in ClO3 = 2- and becomes 0 in O2, loses 2e-, oxidized

Cl 5+ + 6e- Rightwards Arrow Cl-
O 2- Rightwards Arrow O2 + 2e-

to cancel out the electrons, multiply by a multiples of a common factor, in this case, 6
Cl5+ + 6e- Rightwards Arrow Cl-
3O 2- Rightwards Arrow 3O2 + 6e-
cancel out the electrons and combine the elements/compounds

KClO3 Rightwards Arrow KCl + 3O2
wrote...
11 years ago
Except Caroline's equation isn't balanced.

The balanced equation, which you can easily balance by inspection, is...
2KClO3(s) ? 2KCl(s) + 3O2(g)

With all due respect, just a simple look at this one will allow you to balance it by inspection.  Clearly, the number of oxygen atoms on the right hand side must be in multiples of 2, which will always be an even number, and there are three oxygen atoms on the left.  Doubling that number will give you 6, also an even number.  Multiplying O2 by 3 will give you six oxygen atoms, and then balancing K and Cl is trivial.   Using the methods reserved for more complicated redox reactions will simply slow you down.
wrote...
11 years ago
So, where did CM go wrong? Right here:

Cl 5+ + 6e- Rightwards Arrow Cl-
O 2- Rightwards Arrow O2 + 2e-

The second equation isn't balanced for atoms, so let's fix it:

Cl 5+ + 6e- Rightwards Arrow Cl-
O 2- Rightwards Arrow (1/2)O2 + 2e-

Let's use a factor of three to balance the electrons:

Cl 5+ + 6e- Rightwards Arrow Cl-
3O 2- Rightwards Arrow (3/2)O2 + 6e-

Let's combine the equations:

ClO3^- ---> Cl- + (3/2)O2

Notice how I made the chlorate. Now, let's put some potassium ion back in:

KClO3 ---> KCl + (3/2)O2

It's now balanced, but we need to get rid of the fraction, so multiply through by 2:

2KClO3 ---> 2KCl + 3O2

pisgachemist says:

"With all due respect, just a simple look at this one will allow you to balance it by inspection."

He's right, but the point of the question is to learn the oxidation-number change method and that is best done with a simple example. The mch more common method is the half-reaction method. I have lots of discussion about it here:

http://www.chemteam.info/Redox/Redox.html
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