× Didn't find what you were looking for? Ask a question
Top Posters
Since Sunday
a
5
k
5
c
5
B
5
l
5
C
4
s
4
a
4
t
4
i
4
r
4
r
4
New Topic  
tonya_c1977 tonya_c1977
wrote...
Posts: 30
Rep: 0 0
11 years ago
Describe the difference between galvanic cell and an electrochemical cell. Give examples.


I have to write a short essay on this...and i can't seem to really find the difference between them or im not understanding it. help!
Read 443 times
1 Reply

Related Topics

Replies
wrote...
11 years ago
a galvanic cell undergoes the oxidation/reduction reaction upon closing the circuit
it is a spontaneous reaction in which electrons are transfered,
producing a positive voltage,
like discharging a battery
http://en.wikipedia.org/wiki/Galvanic_cell

http://bilbo.chm.uri.edu/CHM112/tables/redpottable.htm
provides the following reduction voltages
reduction: Pb2+(aq) + 2 e- Rightwards Arrow    Pb(s)    Eo = -  0.125  volts
reduction: Sn2+(aq) + 2 e? --->  Sn(s)    Eo = -  0.137  volts


to get an oxidation/reduction reaction, we reverse one of them
reduction: Pb2+(aq) + 2 e- Rightwards Arrow    Pb(s)    Eo = -  0.125  volts
oxidation: Sn(s) --->:  Sn2+(aq) + 2 e?   Eo = +  0.137  volts
this would be a galvanic cell, that redoxs spontaneously, because the net voltage is "+"


had we reversed the other one:
oxidation: Pb(s)  ---> Pb2+(aq) + 2 e-     Eo = + 0.125  volts
reduction: Sn2+(aq) + 2 e? --->  Sn(s)    Eo = -  0.137  volts
this would be an electrochemical cell, that will redox spontaneously, because the net voltage is "-"


an electrolytic cell is one that must be forced, by subjecting it to a supply of DC voltage..
like recharging a battery
http://en.wikipedia.org/wiki/Electrolytic_cell
New Topic      
Explore
Post your homework questions and get free online help from our incredible volunteers
  1383 People Browsing
 107 Signed Up Today
Related Images
  
 998
  
 106
  
 547
Your Opinion
Which 'study break' activity do you find most distracting?
Votes: 741